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Thermodynamics of Materials 材料热力学（英文版）

样章
作者：
蒋青 文子
定价：
59.00元
ISBN：
978-7-04-029610-5
版面字数：
300千字
开本：
16开
全书页数：
298页
装帧形式：
精装
重点项目：
暂无
出版时间：
2011-01-14
读者对象：
学术著作
一级分类：
自然科学
二级分类：
材料
三级分类：
通用

《材料热力学》将材料作为一个整体研究对象，内容涵盖金属、合金、陶瓷、半导体和高分子等所有材料领域的宏观、介观和微观热力学，注重通过材料问题实例来 使读者理解和掌握热力学的基本规律。本书还以较大篇幅介绍了纳米热力学和界面热力学的最新进展，以及相关计算机模拟的最新贡献。

本书适用于所有材料相关领域的科研工作者、工程师和研究生。

作者蒋青博士与文子博士为吉林大学教授。

  • Front Matter
  • Chapter 1 Fundamentals of Thermodynamics
    • 1.1 Thermodynamics of Materials Science, Scope and Special eatures of the Book
    • 1.2 Concepts of Thermodynamics
    • 1.3 Temperature and Zeroth Law of Thermodynamics
    • 1.4 First Law of Thermodynamics
    • 1.5 Entropy and Second Law of Thermodynamics
    • 1.6 General Thermodynamic Relationships
    • 1.7 Third Law of Thermodynamics
    • References
  • Chapter 2 Statistical Thermodynamics
    • 2.1 Basic Concepts
    • 2.2 Classical Statistic Thermodynamics of Independent Particles
    • 2.3 Energy Mode and Energy Levels
    • 2.4 Bose-Einstein and Fermi-Dirac Statistics
    • 2.5 Application of Quantum Statistics
      • 2.5.1 Spatial Con¯guration of Long Chain Polymers
      • 2.5.2 Statistical Thermodynamics of a Paramagnetic Crystal
      • 2.5.3 Negative Temperature
    • References
  • Chapter 3 Heat Capacity, Entropy, and Nanothermodynamics
    • 3.1 Heat Capacity
      • 3.1.1 Relations of Principal Heat Capacities
      • 3.1.2 Magnetic Heat Capacity
      • 3.1.3 Heat Capacity of Lattice Vibration of Solids
      • 3.1.4 Electronic Heat Capacity of Metals
    • 3.2 Entropy
      • 3.2.1 Positional Part of Melting Entropy and Its Evaluation
      • 3.2.2 Contribution of Vibrational Part of Melting Entropy of Semiconductors
      • 3.2.3 Electronic Component of Melting Entropy
    • 3.3 Nanothermodynamics
    • 3.4 Melting Thermodynamics
      • 3.4.1 A Melting Criterion
      • 3.4.2 Existing Models for Size-dependent Melting of rystals
      • 3.4.3 Size-dependent Melting Thermodynamics of rystals
    • 3.5 Cohesive Energy
      • 3.5.1 Size-dependent Cohesive Energy of Crystals
      • 3.5.2 Vacancy Formation Energy and Cohesive Energy of Clusters
    • 3.6 Size E®ect on Bandgap of II-VI Semiconductor Nanocrystals
    • References
  • Chapter 4 Phase Diagrams
    • 4.1 Gibbs Phase Rule and Phase Diagram of Unary System
    • 4.2 Clapeyron Equation in Condensed State Equilibria
    • 4.3 Solution, Partial Molar Properties and Chemical Potential
    • 4.4 Graphical Representation, Ideal and Regular Solutions
    • 4.5 Equilibrium Conditions of Phases and Phase Diagram of Binary Systems
      • 4.5.1 Complete Miscibility, Continuous Binary Solution Phase Diagram and Related Size Dependence
      • 4.5.2 Immiscibility{Two Mechanisms of Phase Transitions
    • 4.6 On Approximation of Gibbs Free Energy Change of Crystallization
    • 4.7 Bandgap Energy of Binary Nanosemiconductor Alloys
    • References
  • Chapter 5 Thermodynamics of Phase Transitions
    • 5.1 Thermodynamic Classi¯cation of Phase Transitions
    • 5.2 Landau and Ising Models for the Second-order Phase Transitions
      • 5.2.1 Landau Model
      • 5.2.2 Ising Model and its Applications
      • 5.2.3 Critical Exponent
    • 5.3 Thermodynamics of Martensitic and Bainite Transitions
    • 5.4 Glass Transition
      • 5.4.1 Freezing into Solid State: Glass Formation versus Crystallization
      • 5.4.2 Characteristic Properties of Glass Transition
      • 5.4.3 Size E®ect on Glass Transition
    • 5.5 Ferromagnetic and Antiferromagnetic Phase Transitions of Nanocrystals
      • 5.5.1 Size-dependent Ordering Temperatures of Ferromagnetic and Antiferromagnetic Nanocrystals
      • 5.5.2 Thermal Stability in Exchange-biased FM/AFM Bilayers
      • 5.5.3 Ferroelectric Phase Transition of Nanocrystals
      • 5.5.4 Superconductive Phase Transition of Nanocrystals
    • References
  • Chapter 6 Thermodynamics of Interfaces
    • 6.1 Point Defect Thermodynamics
    • 6.2 Line Defects Thermodynamics
    • 6.3 Thermodynamics of Interfaces
      • 6.3.1 Thermodynamic Description of Surface Free Energy of Liquids and Solids
      • 6.3.2 Thermodynamics of Surface Stress and Intrinsic Stress
      • 6.3.3 Real Surface: Reconstruction and Relaxation
      • 6.3.4 Equilibrium of Fluid Droplets and Solid Particles
      • 6.3.5 Wul® Construction and Adsorption on Solid Surfaces
    • 6.4 Solid-liquid Interface Energy
      • 6.4.1 Bulk Solid-liquid Interface Energy and That at Melting Points
      • 6.4.2 Size Dependence of Solid-liquid Interface Energy
      • 6.4.3 Nucleus-liquid Interface Energy
    • 6.5 Solid-solid Interface Energy
    • 6.6 Solid-vapor Interface Energy or Surface Energy
      • 6.6.1 Bulk Surface Energy of Elementary Solids
      • 6.6.2 °sv0 of Several Ceramics with NaCl Structure
      • 6.6.3 Size-dependent Surface Energy of Solids
    • 6.7 Liquid-vapor Interface Energy or Surface Tension
      • 6.7.1 Bulk Surface Tension and Its Temperature Coe±cient
      • 6.7.2 Determination of °Lv0(Tm) and ° Lv0(Tm) Values and °Lv0(T) and ° Lv0(T) Functions
      • 6.7.3 Size Dependence of Liquid-vapor Interface Energy
    • 6.8 Applications of Size-dependent Interface Energy
      • 6.8.1 Thermodynamic Phase Stability of Nanocarbons
      • 6.8.2 Static Hysteresis of Solid Transition of CdSe Nanocrystals
      • 6.8.3 Critical Layer Number and Critical Mis¯t of Epitaxial Grown Metallic Thin Films
      • 6.8.4 Reconstruction Possibility of fcc Metallic Surfaces at Room Temperature
    • References
  • Index

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