《材料热力学》将材料作为一个整体研究对象,内容涵盖金属、合金、陶瓷、半导体和高分子等所有材料领域的宏观、介观和微观热力学,注重通过材料问题 实例来 使读者理解和掌握热力学的基本规律。本书还以较大篇幅介绍了纳米热力学和界面热力学的最新进展,以及相关计算机模拟的最新贡献。《材料热力学》适用于所有 材料相关领域的科研工作者、工程师和研究生。
作者蒋青博士与文子博士为吉林大学教授。
- Chapter 1 Fundamentals of Thermodynamics
- 1.1 Thermodynamics of Materials Science, Scope and Special Features of the Book
- 1.2 Concepts of Thermodynamics
- 1.3 Temperature and Zeroth Law of Thermodynamics
- 1.4 First Law of Thermodynamics
- 1.5 Entropy and Second Law of Thermodynamics
- 1.6 General Thermodynamic Relationships
- 1.7 Third Law of Thermodynamics
- References
- Chapter 2 Statistical Thermodynamics
- 2.1 Basic Concepts
- 2.2 Classical Statistic Thermodynamics of Independent Particles
- 2.3 Energy Mode and Energy Levels
- 2.4 Bose-Einstein and Fermi-Dirac Statistics
- 2.5 Application of Quantum Statistics
- 2.5.1 Spatial Configuration of Long Chain Polymers
- 2.5.2 Statistical Thermodynamics of a Paramagnetic Crystal
- 2.5.3 Negative Temperature
- References
- Chapter 3 Heat Capacity, Entropy, and Nanothermodynamics
- 3.1 Heat Capacity
- 3.1.1 Relations of Principal Heat Capacities
- 3.1.2 Magnetic Heat Capacity
- 3.1.3 Heat Capacity of Lattice Vibration of Solids
- 3.1.4 Electronic Heat Capacity of Metals
- 3.2 Entropy
- 3.2.1 Positional Part of Melting Entropy and Its Evaluation
- 3.2.2 Contribution of Vibrational Part of Melting Entropy of Semiconductors
- 3.2.3 Electronic Component of Melting Entropy
- 3.3 Nanothermodynamics
- 3.4 Melting Thermodynamics
- 3.4.1 A Melting Criterion
- 3.4.2 Existing Models for Size-dependent Melting of Crystals
- 3.4.3 Size-dependent Melting Thermodynamics of Crystals
- 3.5 Cohesive Energy
- 3.5.1 Size-dependent Cohesive Energy of Crystals
- 3.5.2 Vacancy Formation Energy and Cohesive Energy of Clusters
- 3.6 Size Effect on Bandgap of II-VI Semiconductor Nanocrystals
- References
- Chapter 4 Phase Diagrams
- 4.1 Gibbs Phase Rule and Phase Diagram of Unary System
- 4.2 Clapeyron. Equation in Condensed State Equilibria
- 4.3 Solution, Partial Molar Properties and Chemical Potential
- 4.4 Graphical Representation, Ideal and Regular Solutions
- 4.5 Equilibrium Conditions of Phases and Phase Diagram of Binary Systems
- 4.5.1 Complete Miscibility, Continuous Binary Solution Phase Diagram and Related Size Dependence
- 4.5.2 Immiscibility-Two Mechanisms of Phase Transitions
- 4.6 On Approximation of Gibbs Free Energy Change of Crystallization
- 4.7 Bandgap Energy of Binary Nanosemiconductor Alloys
- References
- Chapter 5 Thermodynamics of Phase Transitions
- 5.1 Thermodynamic Classification of Phase Transitions
- 5.2 Landau and Ising Models for the Second-order Phase Transitions
- 5.2.1 Landau Model
- 5.2.2 Ising Model and its Applications
- 5.2.3 Critical Exponent
- 5.3 Thermodynamics of Martensitic and Bainite Transitions
- 5.4 Glass Transition
- 5.4.1 Freezing into Solid State: Glass Formation versus Crystallization
- 5.4.2 Characteristic Properties of Glass Transition
- 5.4.3 Size Effect on Glass Transition
- 5.5 Ferromagnetic and Antiferromagnetic Phase Transitions of Nanocrystals
- 5.5.1 Size-dependent Ordering Temperatures of Ferromagnetic and Antiferromagnetic Nanocrystals
- 5.5.2 Thermal Stability in Exchange-biased FM/AFM Bilayers
- 5.5.3 Ferroelectric Phase Transition of Nanocrystals
- 5.5.4 Superconductive Phase Transition of Nanocrystals
- References
- Chapter 6 Thermodynamics of Interfaces
- 6.1 Point Defect Thermodynamics
- 6.2 Line Defects Thermodynamics
- 6.3 Thermodynamics of Interfaces
- 6.3.1 Thermodynamic Description of Surface Free Energy of Liquids and Solids
- 6.3.2 Thermodynamics of Surface Stress and Intrinsic Stress
- 6.3.3 Real Surface: Reconstruction and Relaxation
- 6.3.4 Equilibrium of Fluid Droplets and Solid Particles
- 6.3.5 Wulff Construction and Adsorption on Solid Surfaces
- 6.4 Solid-liquid Interface Energy
- 6.4.1 Bulk Solid-liquid Interface Energy and That at Melting Points
- 6.4.2 Size Dependence of Solid-liquid Interface Energy
- 6.4.3 Nucleus-liquid Interface Energy
- 6.5 Solid-solid Interface Energy
- 6.6 Solid-vapor Interface Energy or Surface Energy
- 6.6.1 Bulk Surface Energy of Elementary Solids
- 6.6.2 %v0 of Several Ceramics with NaC1 Structure
- 6.6.3 Size-dependent Surface Energy of Solids
- 6.7 Liquid-vapor Interface Energy or Surface Tension
- 6.7.1 Bulk Surface Tension and Its Temperature Coefficient
- 6.7.2 Determination of Lv0(Tm) and /Lv0(Tm) Values and Lv0 (T) and /v0 (T) Functions
- 6.7.3 Size Dependence of Liquid-vapor Interface Energy
- 6.8 Applications of Size-dependent Interface Energy
- 6.8.1 Thermodynamic Phase Stability of Nanocarbons
- 6.8.2 Static Hysteresis of Solid Transition of CdSe Nanocrystals
- 6.8.3 Critical Layer Number and Critical Misfit of Epitaxia] Grown Metallic Thin Films
- 6.8.4 Reconstruction Possibility of fcc Metallic Surfaces at Room Temperature
- References